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After I was offered a large amount of europium metal with a nominal value of about 300,000 euros, I wrote this article about the uses - and theft - of europium.


Uses of europium

Various internet sources reported the theft of 460 kilograms of europium oxide from the Kyrgyz Chemical-Mechanical Plant in Central Asia in January of 2003.

europium Apparently, this europium oxide powder had been acquired in the past for intended use in the manufacture of control rods for nuclear reactions.

The theft sounded a bit puzzling to me. When I searched the web, however, I found sites that compare rare earth elements (REEs) to precious metals like gold and platinum and batches of rare earths were offered on various metal auction sites. Europium (Eu) is one of those rare earth elements.

Rare earth elements are indeed very expensive, partly because it is very expensive to extract and concentrate them from their ores. Of all the REEs, europium is reported to be the most expensive.

The thieves might therefore have seen the europium oxide as an investment opportunity, but shares, gold and diamonds – or even a smart piece of real estate - would probably be a lot easier to sell. Unlike with gold and platinum (precious metals), you cannot create jewelry from europium and the average citizen has no use for it. Europium oxide cannot be used to make explosives or nuclear devices either. So what is europium? What is it good for?

Europium is a metal as soft as lead. It can have the divalent oxidation state (mainly in deep rocks) but in the p,T and redox conditions of the earth's surface, it strongly prefers to be trivalent.

That makes the metal highly reactive and, as a result, toxic, corrosive, irritant and particularly flammable. It readily reacts with oxygen and water if not protected and handled carefully (stored under oil, for instance, and kept away from heat).

Wrapped europium metal in various stages of oxidation:
Eu Eu Eu

The metal's oxide is therefore much more stable. Note: This does not mean that anyone who happens to have europium metal in his possession should simply expose it to air.

Europium has many technological uses. Europium complexes are used to distinguish genuine bank notes from falsified ones and have applications in analytical chemistry as well. Examples of other applications of Eu involve CRT and flat screens for color TVs and computers, and laser equipment.

Europium absorbs neutrons quite well, hence its use in control rods in, for example, uranium plants in Russia and Ukraine.

One newer development focuses on the commercial application of this particular (spent) europium (Eu-152, 154 and 155) as a much-needed gamma source for sterilization purposes (against microorganisms). That would take care of this nuclear-waste storage problem as well.

Note that europium's naturally occurring isotopes - Eu-151 and 153 - are not radioactive. However, REEs and actinides - the latter are radioactive - often occur together in nature because of their chemical similarities.





P.S.
See also this article about the use of luminescent europium complexes in Euro notes article about rare earth elements and their use in for instance green technologies. Did you know that the engine of a Toyota Prius contains 1 to 2 kilograms of neodymium?




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